Science

Vacuum Pyrolysis

Direct chemisorption into a lithium alloy of carbonaceous gases produced by controlled thermal degradation of organic materials under vacuum.

Application in Radiocarbon Dating

Benzene Line widely uses vacuum pyrolysis in the benzene production process. The approach (Skripkin and Kovaliukh, 1998) offers the advantage of a single-stage, highly efficient and economical procedure for the production of lithium carbide.

It is applicable for most types of sample material encountered in routine dating work, including organic detritus dispersed in a highly (up to 95% by weight) mineral matrix and/or carbonates. Bone collagen can also be processed without the need for its prior extraction and purification.

Scheme of high temperature reaction vessel — heart of benzene line (1998)

Scheme of high temperature reaction vessel (1998)

Development

The initial idea of vacuum pyrolysis application in radiocarbon dating was published in 1998. Future developments are enclosed in materials used in Benzene Line, and knowledge given in user's manual and during staff training. We use selected materials — Titanium, Teflon, Stainless Steel and Boron-Silicate Glass. Our general approach is to optimize volume (diameter and length) of benzene line. Vacuum pyrolysis fits into the base idea of benzene line — minimization of volume — in a metal reaction vessel.

Novel Applications

  • Capsule technology — produces carbide highly productively; allows obtaining small benzene samples; well applicable for both organic and carbonate samples; cost-effective.
  • Microliner thermodestruction technology — simple and highly productive for any kind of sample material; cost-effective and extremely efficient.

Advantages

Short time of sample processing
2–5× reduction of processing cycle time
High chemical yield for carbon processed
High purity of resulting carbide

Applicable For

  • Different sample materials
  • Different sample matrices (solid, gases, liquid)
  • Fractioning materials
  • Highly contaminated samples
  • Low carbon materials

References

V.V. Skripkin, N.N. Kovaliukh. Recent developments in the procedures used at the SSCER Laboratory for the routine preparation of lithium carbide. RADIOCARBON. Vol 40, No 1 (1998)